Table of Contents

Preface.- The Early Earth Atmosphere and Early Life Catalysts.- Living on Acetylene. A Primordial Energy Source.- Carbon Monoxide. Toxic Gas and Fuel for Anaerobes and Aerobes: Carbon Monoxide Dehydrogenases.- Investigations of the Efficient Electrocatalytic Interconversions of Carbon Dioxide and Carbon Monoxide by Nickel-Containing Carbon Monoxide Dehydrogenases.- Understanding and Harnessing Hydrogenases. Biological Dihydrogen Catalysts.- Biochemistry of Methyl-Coenzyme M Reductase: The Nickel Metalloenzyme that Catalyzes the Final Step in Synthesis and the First Step in Anaerobic Oxidation of the Greenhouse Gas Methane.- Cleaving the N,N Triple Bond: The Transformation of Dinitrogen to Ammonia by Nitrogenases.- No Laughing Matter: The Unmaking of the Greenhouse Gas Dinitrogen Monoxide by Nitrous Oxide Reductase.- The Production of Ammonia by Multiheme Cytochromes c.- Hydrogen Sulfide: A Toxic Gas Produced by Dissimilatory Sulfate Reduction and Consumed by Microbial Oxidation.- Transformations of Dimethylsulfide.- Index.

Reviews

“This book is very well compiled and covers key information regarding small molecules that have an important impact in our environment. … Relevant information is supported by high-quality illustrations and figures, allowing the reader to follow discussions about mechanisms of action, structure and function of metal-active sites, biological cycles or electron pathways. … This book will be an excellent acquisition for chemistry libraries and for researchers and students interested on bioinorganic chemistry, biochemistry or inorganic chemistry.” (Norah Barba-Behrens, Transition Metal Chemistry, Vol. 41, 2016)